
LiFePO4 vs Other Battery Chemistries
| Specification | LiFePO4 | AGM Lead-Acid | Flooded Lead-Acid | Lithium-Ion (NMC) |
|---|---|---|---|---|
| Usable DoD | 80-100% | 50% | 50% | 80-90% |
| Cycle Life | 2,000-5,000 | 300-500 | 300-700 | 500-1,000 |
| Round-trip Efficiency | 92-98% | 80-85% | 75-85% | 85-95% |
| Weight per kWh | ~7 kg | ~25 kg | ~30 kg | ~6 kg |
| Self-discharge/month | 2-3% | 3-5% | 5-15% | 3-5% |
| Thermal Runaway Risk | Very low | None (but gassing risk) | None (but gassing risk) | Moderate |
The usable capacity gap is the key difference. A 100Ah LiFePO4 battery at 80% DoD delivers 80Ah of usable power. A 100Ah AGM at its safe 50% DoD delivers just 50Ah — 37.5% less usable energy from the same amp-hour rating.

The LiFePO4 Voltage Curve Advantage
LiFePO4 cells hold a remarkably flat voltage throughout discharge. A single cell stays between 3.2V and 3.3V from 10% to 90% state of charge. This flat curve means your 12V system delivers nearly constant power whether the battery is nearly full or nearly empty.
Compare that to lead-acid, where a 12V battery drops from 12.7V at full to 11.8V at 50% discharge. That voltage sag reduces the effective wattage available to your devices and makes some sensitive electronics behave erratically.
The practical impact: a LiFePO4-powered inverter maintains consistent AC output right up until the BMS cuts off, while a lead-acid system gradually loses capacity as voltage drops. For devices with minimum voltage requirements — like 12V compressor fridges — LiFePO4 delivers noticeably longer effective runtimes than the raw numbers suggest.
Worked Examples
Upgrading from Lead-Acid to LiFePO4 in an RV
Context
You currently run two 100Ah lead-acid batteries (200Ah) at 50% DoD, giving you 1,056 Wh usable. You want to switch to a single 200Ah LiFePO4 at 80% DoD. Your load is 150W.
Calculation
Lead-acid usable: 200 x 12 x 0.50 x 0.88 = 1,056 Wh → runtime = 7.0 hrs
LiFePO4 usable: 200 x 12 x 0.80 x 0.92 = 1,766 Wh → runtime = 11.8 hrs
Interpretation
The LiFePO4 gives 67% more runtime from the same amp-hour capacity. That is 4.8 extra hours from one battery weighing half as much as the two lead-acid units it replaces.
Takeaway
LiFePO4 wins on usable capacity, weight, and cycle life. To see how fast solar can recharge it, use our solar battery charge time calculator.
Sizing a 48V LiFePO4 Bank for Off-Grid Solar
Context
Your cabin draws 1,500W average for 6 hours per evening (9 kWh). You want one night of autonomy from a 48V LiFePO4 bank at 80% DoD and 90% inverter efficiency.
Calculation
Energy needed: 9,000 Wh / 0.90 eff = 10,000 Wh from battery
At 48V and 80% DoD: 10,000 / (48 x 0.80) = 260.4 Ah minimum
Standard option: 3 x 100Ah 48V modules in parallel (300Ah).
Interpretation
300Ah at 48V gives 11,520 Wh usable — about 28% headroom above the 9 kWh requirement. That margin covers colder nights when battery capacity drops.
Takeaway
After sizing the bank, size the solar array to replenish it daily. Our solar panel and battery sizing calculator handles both sides in one step.
Frequently Asked Questions
Glossary
Lithium Iron Phosphate
A lithium battery chemistry (LiFePO4) known for exceptional safety, long cycle life (3,000-5,000 cycles), and flat discharge voltage. It is heavier per kWh than other lithium chemistries but does not suffer thermal runaway.
Battery Management System
An electronic circuit built into LiFePO4 batteries that monitors voltage, current, and temperature of each cell. It prevents overcharging, over-discharging, and short circuits. Without a BMS, individual cells can become dangerously unbalanced.
Flat Discharge Curve
LiFePO4 batteries maintain a nearly constant voltage (around 13.2V for a 12V battery) through most of the discharge cycle. This means your devices receive stable power from full charge down to 80% DoD, unlike lead-acid which sags progressively.
Sizing a solar system for your LiFePO4 battery bank? Our <a href="/solar/solar-battery-bank-size-calculator">solar battery bank size calculator</a> helps you match panels to storage.
Related calculators
12V Battery Runtime Calculator
Calculate how long a 12 volt battery lasts under any load. Pre-tuned for 12V deep cycle, AGM, and LiFePO4 systems.
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AGM Battery Runtime Calculator
Estimate AGM battery discharge time with chemistry-specific defaults. Compare AGM vs flooded lead-acid for your use case.
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Battery Capacity (Amp Hours) Calculator
Calculate battery capacity in amp-hours from watt-hours and voltage. Convert between Wh, Ah, and watts easily.
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LiFePO4 dominates the off-grid and mobile power space for good reason. Higher usable capacity, longer cycle life, and flat voltage output make it the best chemistry for most applications — provided you can handle the upfront cost. Run your numbers above, then check whether the cost-per-cycle math works for your use case. For a side-by-side chemistry breakdown, read our LiFePO4 vs lead-acid runtime comparison. If AGM is on your shortlist, the AGM runtime calculator uses AGM-specific defaults. And for applications needing heavy cycling on a budget, check the deep cycle runtime calculator which covers flooded and gel types too.
Last updated:
Written and maintained by Dan Dadovic, Commercial Director at Ezoic Inc. & PhD Candidate in Information Sciences. He works professionally as Commercial Director at Ezoic Inc., leading revenue strategy across digital publishing.
Disclaimer: Calculator results are estimates based on theoretical formulas. Actual performance varies with temperature, battery age, load patterns, and equipment condition. For critical electrical work, consult a licensed electrician.